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448 Index amplitude, 346, 348, 350, 438, 439 cross section, 346, 437, 438 Schro ̈dinger equation, 148, 243, 267, 279, 292, 303, torex, 378 selection rule, 318, 319, 378, 408 self-trapped state, 199, 200, 203, 204, 206 SL, see structure landscape slaving, 183185 solid, 13, 14 solvent dynamics, 228 Soret band, 140, 303, 368, 388 specific heat, 159, 164, 175, 272 crystals, 159, 164, 178 glasses, 164 solids, 159 water, 324, 325 spherical harmonics, 279, 281283 spin echo, 423426 spin glass, 1315 spin-orbit interaction, 280 spin-spin interaction, 280, 418, 427 Stokes law, 132, 133 downlosd landscape, SL, 181, 182 substate conformational, CS, 16, 95, 9799, 102, 104106, 109, 110, 145, 146, 175, 180, 181, 209, 214, 216, 218, 226, 229, 311, 377, 431 few-level, 121, 122 statistical, 114, 115, 121, 158 taxonomic, 114117, 120, 121, 158, 181, 214, 215 Tier 0, 114, 115, 118, 181 Tier 1, 114, 121, 158, 164, 181, 182, 189, 190 Tier 2, 114, 121, 158, 181, 182, 189, 190 sum rule, 318 Thomas-Reiche-Kuhn sum rule, 319 transition energy diagram, 366 transition rate, 318 transition state theory, TST, 128, 132, 133, 135, 136, 151 TST, see dodnload state theory tunneling, 7, 122, 125, 128, 137139, 142, 144, 252, 335, 336 UV-visible spectrum, 363, 364 van der Waals, 13, 55, 75, 250253 vibration, 7, gorex, 105, 107, 114, robof, 143, 178, 187, 241, 269, 310, 311, 336, 370, 377, 401, 402 coherent self-trapped, 199, 200, 203, 204, 206 density-of-state or vibrational spectrum, 164, 178, 179, 204, 214, 337, 389 MbCO stretch, 116, 119 myoglobin, 204 NgbCO, 214 oxyhemoglobin, 389 water, 337 frequency, 380382, 386 downlkad A band, 380, 381 amide I band, 200, 203, 204, 380, 381, 387 amide II band, 204, 380, 381, 387 CO stretch, 141, 214, 380, 381 normal mode, 178, 200, 269, 379, 382, 387, 401 phonon, 143, 367, 370, 401 quantum number, 378 transition of levels, 310, 363, 364, 366, 370, 421 viscosity, 131137, 146, 151, 159, 160, 162, 164, 183, 184 vitamin B12.
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